منابع مشابه
Theoretical Study of Heteroatom Resonance-Assisted Hydrogen Bond: Effect of Substituent on π-delocalization
The concept of Resonance Assisted Hydrogen Bond (RAHB), which usually occurs in b diketons, has a remarkable role in chemistry. These molecules, which contain heteroatom particularly O and N, are species with biological interest in protein folding and DNA pairing. Therefore, the amplification of hydrogen bonds strength by substituents may be important in life scie...
متن کاملExperimental Observation of Resonance-Assisted Tunneling.
We present the first experimental observation of resonance-assisted tunneling, a wave phenomenon, where regular-to-chaotic tunneling is strongly enhanced by the presence of a classical nonlinear resonance chain. For this we use a microwave cavity made of oxygen free copper with the shape of a desymmetrized cosine billiard designed with a large nonlinear resonance chain in the regular region. It...
متن کاملNMR Resonance Assignment Assisted by Mass Spectrometry
Nuclear magnetic resonance (NMR) provides a useful tool for the structural determination of biomollecules, especially for those molecules that are difficult to crystallize for diffraction studies. During the structure determination by NMR, a key step is the resonance assignment of chemical shifts. The traditional NMR resonance assignment is to use the triple resonance experiments, such as HNCA,...
متن کاملResonance-assisted tunneling in near-integrable systems.
Dynamical tunneling between symmetry related invariant tori is studied in the near-integrable regime. Using the kicked Harper model as an illustration, we show that the exponential decay of the wave functions in the classically forbidden region is modified due to coupling processes that are mediated by classical resonances. This mechanism leads to a substantial deviation of the splitting betwee...
متن کاملNovel Resonance - Assisted Electromagnetic - Transport Phenomena
We first demonstrate theoretically and experimentally that electromagnetic resonators with high quality factors (Q) can be used to transfer power efficiently over distances substantially larger than the characteristic dimensions of the resonators by operating in a so-called "strongly coupled" regime. We next generalize the notion of strongly coupled resonances to a system comprising one power s...
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ژورنال
عنوان ژورنال: The Journal of the Acoustical Society of America
سال: 1974
ISSN: 0001-4966
DOI: 10.1121/1.1919632